LO3 - Chemical Energetics - Questions

Carboxyl2 minutes read

Nitrogen monoxide is an atmospheric pollutant causing irritation, formed in car engines through a reaction between nitrogen and oxygen. Understanding energy profiles, activation energy, and bond energy calculations are crucial in differentiating between endothermic and exothermic reactions, with catalysts playing a key role in speeding up reactions by lowering activation energy.

Insights

  • Positive enthalpy change in a reaction signifies that more energy is needed to break bonds than is released during bond formation, indicating an endothermic process where products have higher energy levels than reactants.
  • Catalysts play a crucial role in accelerating reactions by reducing the activation energy required for the reaction to occur, facilitating faster transformations without being consumed in the process.

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Recent questions

  • What is the role of activation energy in catalyzed reactions?

    Activation energy in catalyzed reactions is lowered by catalysts, speeding up the reaction without being consumed.

  • How can one differentiate between endothermic and exothermic reactions?

    Endothermic reactions absorb heat energy, while exothermic reactions release heat energy.

  • What is the significance of enthalpy change in chemical reactions?

    Enthalpy change indicates the energy absorbed or released during bond formation and breaking.

  • How are energy profile diagrams used to analyze reactions?

    Energy profile diagrams depict reactants, products, enthalpy change, and activation energy in reactions.

  • How do bond energy calculations contribute to understanding reactions?

    Bond energy calculations involve determining the energy required to break and form specific bonds in a reaction.

Related videos

Summary

00:00

Energy Changes in Chemical Reactions

  • Starting the recording with MCQs and the third question
  • Nitrogen monoxide as an atmospheric pollutant causing irritation
  • Formed in car engines by nitrogen and oxygen reaction
  • Positive enthalpy change indicates endothermic reaction
  • Analyzing energy taken in and given out for endo and exo reactions
  • Photosynthesis process involving carbon dioxide and water
  • Activation energy and enthalpy change in catalyzed reactions
  • Increase in particle energy in reactions due to temperature rise
  • Differentiating between endo and exo reactions based on bond breaking and formation
  • Understanding energy profile diagrams and activation energy for reactions

16:09

Understanding Enthalpy Change and Bond Energy

  • Activation energy of the reverse reaction is +447 for the forward reaction and the reactant becomes the product in the reverse reaction.
  • Activation energy is never negative as energy is a scalar quantity, and in enthalpy change, negative values are adjusted.
  • Positive enthalpy change in a reaction indicates that the energy needed to break bonds is greater than the energy released during bond formation.
  • In an endothermic reaction, the products are at a higher energy level than the reactants due to the heat energy absorbed.
  • The energy profile diagram for reactions should include reactants, products, enthalpy change, and activation energy.
  • The examiner may specify whether to label reactants or products in the energy profile diagram.
  • Endothermic reactions involve more energy taken in during bond breaking than given out during bond formation.
  • Bond energy calculations involve determining the energy required to break and form specific bonds in a reaction.
  • Enthalpy change in a reaction can be calculated by subtracting the energy released from the energy absorbed during bond formation and breaking.
  • The enthalpy change in a reaction can be used to calculate the bond energy of specific bonds, such as the bond between carbon and oxygen in carbon monoxide.

32:19

Bond Energy Shifts, Energy Calculations in Chemistry

  • Bond energy cannot be negative; it shifts from negative to positive when a bond is formed and released.
  • To calculate energy released during sulfur burning, convert moles to mass using molar mass.
  • When one mole of sulfur burns, it releases 247 kJ of energy; calculate energy for 0.3 moles.
  • Energy taken in during bond breaking is more than energy given out during bond formation.
  • Calculate energy needed to break specific bonds by multiplying the number of bonds with their respective energies.
  • Calculate total energy required to break one mole of iodine and chlorine bonds.
  • Enthalpy change is calculated by subtracting energy given out during bond formation from energy taken in during bond breaking.
  • Calculate energy released when hydrogen peroxide burns by converting moles to mass and using energy values.
  • Catalysts speed up reactions by lowering activation energy without being consumed in the process.
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