Thermochemistry Equations & Formulas - Lecture Review & Practice Problems

The Organic Chemistry Tutor15 minutes read

The text explains the internal energy change equation, including the components of heat energy (Q) and work (W), and how they affect the system. It also delves into heat energy calculations, balancing combustion reactions, and estimating enthalpy and entropy values for reactions using specific methods, with the final entropy value calculated at 800.

Insights

  • Heat (Q) represents energy transfer due to temperature differences, with positive values indicating absorption by the system in endothermic processes and release to the surroundings in exothermic processes, measured in Joules or calories.
  • Work (W) contributes to the system's internal energy change, being positive when work is done on the system and negative when done by the system, with gas expansion leading to negative work and compression to positive work.

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Recent questions

  • What is the equation for internal energy change?

    ΔU = Q + W

  • How is heat energy represented in the internal energy change equation?

    Q represents heat energy entering or leaving the system; heat flows from hot to cold.

  • How is work denoted in the internal energy change equation?

    Work (W) is positive when done on a system and negative when done by the system.

  • How is heat energy calculated for temperature changes?

    Heat energy calculations: Q = mcΔT for temperature changes.

  • How can the entropy of a reaction be determined using Hess's Law?

    To find the entropy of a reaction, use Hess's Law by modifying and combining two given equations.

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Summary

00:00

Understanding Internal Energy Changes in Thermodynamics

  • Internal energy change equation: ΔU = Q + W
  • Q represents heat energy entering or leaving the system; heat flows from hot to cold.
  • Q is positive for surroundings in endothermic processes and negative for the system in exothermic processes.
  • Q is typically measured in Joules, with 1 kJ = 1,000 J and 1 calorie = 4.184 J.
  • Work (W) is positive when done on a system and negative when done by the system.
  • Gas expansion leads to negative work, while compression results in positive work.
  • Doing work on a system increases its internal energy, while work done by the system decreases it.
  • Heat energy calculations: Q = mcΔT for temperature changes, Q = mΔH for phase changes.
  • Balancing combustion reactions and calculating heat energy released or absorbed.
  • Estimating the enthalpy of a reaction using heat of formation values for products and reactants.

19:18

Calculating Entropy Using Hess's Law

  • To find the entropy of a reaction, use Hess's Law by modifying and combining two given equations. Multiply the first equation by 2 to match the required coefficients, adjust the enthalpy accordingly. Reverse the second equation, changing the sign of the enthalpy. Adding the modified equations results in the desired equation, allowing the calculation of the entropy of the reaction, which in this case is 800.
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