Introduction to Gibbs free energy | Applications of thermodynamics | AP Chemistry | Khan Academy
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Gibbs Free Energy is represented by G, with the formula for delta G being delta H minus (temperature in Kelvin times delta S), determining thermodynamic favorability based on the sign of delta G. A process is favored in the forward direction when delta G is less than zero, leading to spontaneous reactions, while delta G greater than zero indicates non-spontaneity in the forward direction.
Insights
- Delta G determines whether a process is thermodynamically favorable (negative), unfavorable (positive), or at equilibrium (zero), based on the relationship between enthalpy (delta H), entropy (delta S), and temperature.
- The standard state conditions for calculating delta G naught involve pure substances at specific pressures and concentrations, with the equilibrium point reached when delta G equals zero, indicating a balanced process.
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Recent questions
What is Gibbs Free Energy?
The Gibbs Free Energy, denoted as G, represents the energy available to do work in a system at constant temperature and pressure. It is a thermodynamic potential that combines enthalpy and entropy to predict whether a reaction will be spontaneous or non-spontaneous.
How is delta G calculated?
Delta G, the change in Gibbs Free Energy, is calculated using the formula delta G = delta H - (T * delta S), where delta H is the change in enthalpy, T is the temperature in Kelvin, and delta S is the change in entropy. This equation helps determine the spontaneity of a reaction based on the energy changes involved.
What does delta G less than zero indicate?
When delta G is less than zero, it signifies that a process is favored in the forward direction, indicating thermodynamic favorability. This condition suggests that the reaction will occur spontaneously, releasing energy in the process.
What happens when delta G is greater than zero?
If delta G is greater than zero, the process is favored in the reverse direction, indicating non-spontaneity in the forward direction. In this scenario, the reaction requires an input of energy to proceed, making it less likely to occur spontaneously.
What is the significance of delta G at equilibrium?
At equilibrium, when delta G equals zero, the process is balanced, and there is no net change occurring. This state indicates that the forward and reverse reactions are proceeding at equal rates, resulting in a dynamic equilibrium. The standard state conditions for substances play a crucial role in determining the equilibrium state of a reaction.
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