ELECTROCHEMISTRY in 1 Shot: All Concepts, Tricks & PYQs | NEET Crash Course

Competition Wallah117 minutes read

Focus on Electro Chemistry in lectures with potential for 25-30 marks, emphasizing topics like Electro Chemistry, Kinetics, Solutions, and Chemicals while understanding crucial concepts like electrode potential and Faraday's Law in electrolysis for exam preparation. Anode and cathode play essential roles in electrochemical cell reactions, determining the substances that will be reduced or oxidized based on their reduction or oxidation potentials, alongside the formation of valuable secondary batteries like Nickel Cadmium Cells for efficient energy production.

Insights

  • Understanding Electro Chemistry is crucial for exams as it holds the potential for 25-30 marks, focusing on topics like electrochemical cell formation, anode, cathode, and salt bridge functions.
  • The text elaborates on the concept of reduction potential, oxidation potential, and balancing charges in redox reactions, emphasizing the importance of knowing the tendencies of species to get reduced or oxidized based on their potential.
  • Faraday's constant plays a significant role in electrochemistry, aiding in calculations related to oxidation potential, cost, and mass deposited during electrolysis, with the reduction potential at the cathode dictating the substance to be reduced and the product of electrolysis.

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Recent questions

  • What is the importance of Electro Chemistry?

    Electro Chemistry is crucial for exams, offering potential for 25-30 marks. It focuses on key chapters like Electro Chemistry, Kinetics, Solutions, and Chemicals. Understanding these topics is essential for exam preparation, emphasizing practice and self-belief. The text delves into electrochemical cell formation, explaining the roles of anode for oxidation, cathode for reduction, and salt bridge for circuit completion. Representation of cell reactions with anode, bridge, and cathode is detailed, stressing the significance of balancing charges in redox reactions. The concept of reduction potential, oxidation potential, and electrode potential is explained, highlighting the tendency of species to get reduced or oxidized based on their potential. The text also discusses the standard EMF of a cell, calculation of cell potential, and the importance of understanding anode and cathode reactions in electrochemistry.

  • How are electrochemical cells represented?

    Electrochemical cells are represented with anode, bridge, and cathode to showcase the flow of electrons and current based on external voltage. The text explains the impact of external voltage on electrochemical cells, detailing the conditions under which an electrolytic cell is formed. It emphasizes the role of a salt bridge in completing the circuit and preventing reactions from becoming unbalanced. The conditions for electrolytes used in a salt bridge are discussed, highlighting the importance of preventing reactions and ensuring equal ionic mobility. The text also touches on electrode potential, explaining the nature of potential depending on temperature, concentration, and the type of electrode. Understanding the representation of reactions in terms of cell representation is crucial in electrochemistry.

  • What is the significance of reduction potential?

    Reduction potential plays a vital role in electrochemistry, determining the tendency of species to get reduced based on their potential. The text explains the distinction between reduction potential and standard potential, emphasizing the importance of understanding the reduction tendency of species. It details the concept of reduction potential and oxidation potential, focusing on the tendency of species to get reduced or oxidized based on their potential. The text mentions that a high reduction tendency indicates being a good reducing agent, highlighting the importance of reduction potential in determining the behavior of species in electrochemical reactions.

  • How are oxidation and reduction potentials calculated?

    Oxidation and reduction potentials are calculated based on specific formulas and values. The text mentions the process of calculating oxidation potential by subtracting values and performing further calculations. It explains the cost calculation based on the given values and the Magni Doodle method used to compare oxidation and reduction potentials. The text also discusses the standard EMF of a cell, detailing the calculation based on reduction potential and the formula for determining cell potential. Understanding the calculations involved in oxidation and reduction potentials is essential in electrochemistry to analyze the behavior of species in different reactions.

  • What are the key differences between primary and secondary batteries?

    Primary batteries are disposable, while secondary batteries are rechargeable and can be used multiple times. The text mentions Devices Amalgam, a paste of HG and carbon with electrolytes, generating a voltage of 1.35 volts. It explains the reactions at the cathode and anode in secondary batteries like lead storage battery and Nickel Cadmium Cell, highlighting the efficiency of fuel cells using hydrogen and oxygen to produce electrical energy. Understanding the differences between primary and secondary batteries is crucial in determining their applications and advantages in various devices and systems.

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Summary

00:00

"Electro Chemistry: Key Exam Topics Explained"

  • Major revision completed, focusing on Electro Chemistry.
  • Recorded lectures available for flexible learning pace.
  • Electro Chemistry crucial for exams, with potential for 25-30 marks.
  • Focus on three key chapters: Electro Chemistry, Kinetics, Solutions and Chemicals.
  • Emphasis on practice and self-belief for exam preparation.
  • Electro Chemistry and Chemical Kinetics essential topics.
  • Detailed explanation of electrochemical cell formation.
  • Anode for oxidation, cathode for reduction in electrochemical cell.
  • Salt bridge crucial for completing the circuit in electrochemical cell.
  • Representation of electrochemical cell reactions with anode, bridge, and cathode.

12:52

Balancing Charges in Redox Reactions: Essential Concepts

  • The text discusses the concept of balancing charges in redox reactions, emphasizing the importance of charge balance.
  • It mentions the representation of reactions in terms of cell representation and the significance of understanding anode and cathode reactions.
  • The example of a zinc-copper cell is highlighted as a favorite example from NCERT, explaining the representation of reactions and the voltage generated.
  • The text delves into the impact of external voltage on electrochemical cells, detailing the conditions under which an electrolytic cell is formed.
  • It explains the flow of electrons and current in different scenarios based on external voltage, leading to the conversion of an electrochemical cell into an electrolytic cell.
  • The role and function of a salt bridge in completing the circuit and preventing reactions from becoming unbalanced are discussed.
  • The text elaborates on the conditions for electrolytes used in a salt bridge, emphasizing the importance of preventing reactions and ensuring equal ionic mobility.
  • It touches on electrode potential, highlighting the nature of potential depending on temperature, concentration, and the type of electrode.
  • The distinction between reduction potential and standard potential is explained, emphasizing the tendency of species to get reduced based on their potential.
  • The concept of reduction potential and oxidation potential is detailed, focusing on the tendency of species to get reduced or oxidized based on their potential.

25:45

Comparing Oxidation and Reduction Potentials in Electrochemistry

  • Oxidation tendency is called oxidant, while reduction tendency is called reducer.
  • A high reduction tendency indicates being a good reducing agent.
  • Magni Doodle is used to compare oxidation and reduction potentials.
  • The electrochemical series arranges metals based on their reduction potentials.
  • Metals with reduction potentials higher than hydrogen can convert hydrogen into oxides.
  • The standard EMF of a cell is defined when no current is drawn, with specific concentrations and pressures.
  • Anode oxidation potential and cathode reduction potential are added to determine the cell potential.
  • The formula for cell potential is cathode potential minus anode potential.
  • The standard EMF of a cell is calculated based on reduction potential.
  • Questions in electrochemistry involve determining oxidation and reduction potentials for different reactions.

39:12

Iron and Iodine Redox Potential Analysis

  • Iron reduction involves taking iron and iodine to form i2
  • The oxidation of iron is 0.77
  • The reduction is 1
  • Iodine calculation results in -0.536
  • No need to calculate further
  • The best combination is determined by the highest potential
  • The anode in a battery contains the highest oxidation
  • The cathode has the highest reduction potential
  • The highest potential is at the cathode
  • Faraday's constant is 96500 coulombs per mole of electrons

52:32

Electrochemical Calculations and Energy Conservation

  • Oxidation potential calculation: 0.44 minus, then minus becomes plus, followed by 2 * 96500 * 0.10.
  • Resulting value: 100, further calculations lead to 19.3.
  • Cost calculation: If 19.3 kg of juice is given, divide by 1000 to get the cost.
  • Equilibrium constant and delta g: Discusses the value of delta g, rho delta g0, and equilibrium constant.
  • Electrode potential: Explains the importance of hydrogen electrode as a reference for electrode potential.
  • Platinum electrodes: Discusses the use of platinum electrodes in electrochemical cells.
  • Concentration cell: Details the concept of a concentration cell using hydrogen as an example.
  • Oxidation potential of hydrogen electrode: Explains the formula and calculations for oxidation potential.
  • Standard EMF calculation: Demonstrates the calculation of standard EMF in electrochemical cells.
  • Conservation of energy: Discusses the conservation of energy in electrochemical reactions and the calculation of EMF based on changes in electrons.

01:05:24

Calculating Conductivity Values in Chemistry

  • The value of 0.87 will come after calculations.
  • The process involves calculations with values like 0.036, 0.18, and 0.88.
  • The result will be 0.77.
  • The equation involves adding and subtracting values like 0.77 and 2.
  • The standard emf remains the same when multiplied by two.
  • Conductivity in electrolytes is explained, involving ions and factors like temperature.
  • The nature and structure of metals affect conductance.
  • Conductance in chemistry differs from physics due to the flow of ions.
  • Molar conductivity is represented by Lada M and is calculated based on concentration.
  • Equivalent conductivity is related to molar conductivity and involves the n factor in redox reactions.

01:18:52

"Conductivity and Molar Calculations in Electrolytes"

  • Molar conductivity calculation requires concentration and kappa values.
  • To calculate Lada A, divide 1000 by the concentration if in centimeters.
  • The value of 0.024 * 1000 divided by the concentration is 0.20.
  • Resistance of a conductivity cell can be found using the formula r1 * k1 = r2 * k2.
  • Conductivity and molar conductivity calculations are essential.
  • Conductivity decreases with a decrease in concentration for both weak and strong electrolytes.
  • Molar conductivity increases with dilution due to volume increase.
  • Strong electrolytes exhibit a linear relationship between Lada A and concentration.
  • Limiting molar conductivity reaches its maximum value as concentration approaches zero.
  • The degree of dissociation can be calculated using Lda m / Lda m0 for weak acids.

01:33:57

Chemistry: Calculations, Charges, and Conductivity

  • The sum of 8 and 37 is 45.
  • The cost of 858 is being discussed.
  • Equivalent conductivity will decrease to zero.
  • Molar conductivity divided by the n factor is being calculated.
  • The charge of one iron is +3, while two irons have a charge of +6.
  • The process of removing sulphate ions is mentioned.
  • The method to eliminate A is being discussed.
  • The value of Gai A is 9.
  • The process of finding the dissociation constant in acetic acid is explained.
  • Faraday's Law is mentioned in the context of electrolysis.

01:46:31

Calculating Mass Deposited in Electrolysis Reactions

  • To calculate the mass deposited when 0.5 amps pass through silver nitrate, use the formula molar mass = n*f*i*t, where n is the n factor of silver nitrate.
  • The value of current is 0.5 amps, and the time taken is 10 minutes, which should be converted to seconds for accurate calculations.
  • By substituting the values into the formula, the mass deposited is calculated to be 0.336 grams.
  • Faraday's second law of electrolysis states that when the same charge passes through, the ratio of mass deposited will be equal to the ratio of equivalent masses.
  • The ratio of equivalent masses is determined by dividing the molar mass of the substance by its n factor.
  • The reduction potential at the cathode determines which substance will be reduced; choose the substance with the higher reduction potential.
  • The product of electrolysis at the cathode is determined by the substance with the higher reduction potential.
  • At the anode, the substance with the higher oxidation potential will be oxidized to form the product of electrolysis.
  • The preferential discharge order dictates which substance will be discharged first based on their reduction or oxidation potentials.
  • Primary batteries are disposable, while secondary batteries are rechargeable and can be used multiple times.

02:00:16

"Amalgam Devices: Generating Voltage in Batteries"

  • Devices Amalgam is a paste of HG and carbon, with electrolytes, generating a voltage of 1.35 volts.
  • Zinc amalgam at the cathode will produce zinc oxide and H2O in button cells known for their constant cell potential.
  • Secondary batteries like lead storage battery and Nickel Cadmium Cell have specific reactions at the cathode and anode, with fuel cells using hydrogen and oxygen to produce electrical energy efficiently.
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