CHEMICAL KINETICS in 70 minutes || Complete Chapter for NEET

Competition Wallah2 minutes read

Chapter 12 of the map series delves into chemical characters, focusing on reaction rates, temperature, and catalyst effects, crucial for exam preparation. The text covers essential topics like rate law, reaction rates, and temperature-dependent rates in chemical kinetics and highlights factors like activation energy, catalysts, and temperature fluctuations impacting reaction rates.

Insights

  • Chemical kinetics studies reaction rates, calculating them by subtracting initial reactant concentration from final concentration over time. The rate of reaction is always positive and typically measured in liters per mole per second, with different formulas based on concentration, moles, or mass.
  • The chapter delves into the complexities of reactions, focusing on factors like activation energy, temperature, and catalyst effects that affect reaction rates. The Collision Theory and Arrhenius Factor play crucial roles in understanding how reactions occur, emphasizing the importance of various factors like concentration, surface area, and temperature in determining reaction rates.

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Recent questions

  • What is chemical kinetics?

    The study of reaction rates and speed.

  • How is the rate of reaction calculated?

    By subtracting initial from final concentration over time.

  • What is the difference between average and instantaneous rate of reaction?

    Average rate considers overall change, while instantaneous rate is at a specific moment.

  • What is the Arrhenius Factor?

    It determines activation energy and influences reaction rates.

  • How do catalysts affect reaction rates?

    Catalysts lower activation energy, speeding up reactions.

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Summary

00:00

Chemical Kinetics: Rates, Reactions, and Formulas

  • Chapter 12 of the map series focuses on chemical characters, detailing the rate of reactions, temperature, and catalyst effects.
  • The chapter is crucial for exams, with a minimum of two questions expected, taking around half an hour to complete.
  • After finishing the chapter, it's recommended to review short notes and practice questions, including previous year questions.
  • The chapter is divided into four portions, covering the rate of reaction, rate law, and temperature-dependent rates.
  • Chemical kinetics is the study of reaction rates, with a focus on the speed of reactions and the rate of change in concentration over time.
  • The rate of reaction is calculated by subtracting initial reactant concentration from final reactant concentration, divided by the time taken.
  • The rate of reaction is always a positive quantity, with the plus sign representing the appearance of the product.
  • The unit of reaction rate is typically in liters per mole per second.
  • Different formulas are used to calculate the rate of reaction based on concentration, number of moles, or mass.
  • It's essential to understand the difference between average rate and instantaneous rate of reaction for a comprehensive grasp of chemical kinetics.

14:20

Understanding Reaction Rates and Order Experiments

  • The average rate of reaction is discussed, with a focus on changes in time and reactants.
  • Instantaneous rate of reaction is highlighted as a key concept, with VM being a method to calculate it.
  • The rate of reaction is detailed in terms of individual components like A, B, C, and D.
  • The rate law expression is explained, emphasizing the power of reactants in determining the rate of reaction.
  • The order of reaction is explored, with examples of how concentration changes impact the rate.
  • Experimental methods for determining the order of reaction are outlined, including the impact of concentration changes on the rate.
  • The concept of power in reaction rates is discussed, with examples of how doubling concentrations affect the rate.
  • Experiments are detailed as a method to determine the order of reaction, showcasing the impact of constant values on the rate.
  • The importance of experimental orders in understanding reaction rates is emphasized, with practical examples provided.
  • The significance of orders in reaction rates is reiterated, highlighting the experimental nature of determining these values.

29:48

"Chemical Reactions: Rates, Equilibrium, and Laws"

  • Mathematics power can never be zero; it can be negative or a fraction.
  • Order of reaction in multi-step reactions is defined by the slowest step reactant.
  • The unit of rate can be found as a constant, known as the rate constant.
  • Molecularity refers to the number of molecular species undergoing a reaction or collision.
  • For elementary reactions, molecularity is easily determined by the number of molecules reacting.
  • Equilibrium is reached when the rate of the forward reaction equals the rate of the backward reaction.
  • Integrated rate laws relate the concentration of reactants with time in reactions.
  • Zero-order reactions have a fixed rate that is not affected by concentration.
  • Half-life in zero-order reactions is when 50% of the reactant is consumed.
  • First-order reactions have a unique rate of reaction, with a specific formula for calculations and graphing.

45:56

Graphs of Sir L N Aarti and Time

  • The text discusses graphs of Sir L N Aarti and their relation to time.
  • It questions the head graph of mines and the slope.
  • People of the mines and the intersect are also mentioned.
  • The text delves into the graph of time t and the slope of A=K.
  • It talks about gas slope and Locke's graph.
  • Calculations are emphasized, with expressions and numerical solutions.
  • The text explores zero order and first order differences, including half-life calculations.
  • It highlights the completion time and average life of reactions.
  • The concept of pressure in terms of reactions is discussed, along with special cases.
  • The text concludes with the temperature dependency of reaction rates.

01:01:35

Temperature and Activation Energy in Reaction Rates

  • Using Sir Temperature Coefficient to calculate temperature by 10 Kelvin will result in a rise in temperature when dividing the temperature by T+10.
  • The rate constant, P+ Rate constant rate divided by 10, will typically increase when its value at Constant T + 10 is between double and triple or more, leading to a temperature increase.
  • The Arrhenius Factor, also known as the pre-exponential factor, is crucial in determining activation energy, which is non today.
  • Activation energy, represented by A*power of A Mines upon RT, influences the rate of reaction; an increase in activation energy leads to a decrease in the rate of reaction.
  • The presence of a catalyst reduces activation energy, making the reaction pathway easier and shorter, resulting in decreased values.
  • Temperature fluctuations affect the rate of reaction, with the Arrhenius Factor playing a significant role in determining the rate.
  • The Collision Theory, developed after Arrhenius, focuses on effective collisions and energy barriers to ensure proper orientation for successful product formation.
  • The rate of reaction depends on various factors, including the physical state of reactants, concentration, surface area, activation energy, and temperature, influencing the order of reaction and overall rate.
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