11th CHEMISTRY |Chapter no 3 BASIC ANALYTICAL TECHNIQUES | ONESHOT 🎯 | PRADEEP GIRI SIR

Pradeep Giri 11th and 12th Academy・2 minutes read

The video provides an overview of basic analytical techniques essential for chemistry students, detailing purification methods such as filtration, suction filtration, crystallization, and distillation. These methods are crucial for separating and purifying substances based on their physical properties, such as solubility and boiling points, to achieve pure solid samples and compounds.

Insights

  • The video outlines essential purification techniques in chemistry, including filtration, suction filtration, crystallization, and fractional crystallization, emphasizing their importance for students in higher education. For instance, suction filtration employs a Buckner funnel and vacuum pump to effectively remove moisture and impurities from small solid particles, showcasing the practical application of these methods in laboratory settings.
  • Additionally, the text details various distillation methods, such as simple and fractional distillation, which are crucial for separating liquids based on their boiling points. Distillation under reduced pressure is highlighted as a technique that allows for the purification of high boiling point substances at lower temperatures, preventing the decomposition of sensitive compounds, thus broadening the understanding of advanced separation processes in chemistry.

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Recent questions

  • What is the definition of distillation?

    Distillation is a separation process that involves converting a liquid into vapor and then back into liquid. This technique is commonly used to purify liquids based on their boiling points. The process typically includes heating a liquid mixture in a round bottom flask until it reaches its boiling point, at which point the vapor rises into a condenser. The condenser cools the vapor, allowing it to condense back into liquid form, which is then collected in a separate container. Distillation can be performed in several ways, including simple distillation, fractional distillation, and distillation under reduced pressure, each suited for different types of mixtures and boiling point differences.

  • How does chromatography work?

    Chromatography is a sophisticated separation technique that relies on the differential affinities of compounds for a stationary phase and a mobile phase. In this method, a mixture is placed on a stationary phase, which can be a solid or a liquid coated on a solid support. A mobile phase, which is typically a liquid or gas, is then passed through the stationary phase. As the mobile phase moves, different components of the mixture travel at different rates based on their interactions with the stationary phase, leading to separation. This technique is widely used in laboratories for purifying substances and analyzing complex mixtures, with various forms such as thin layer chromatography and column chromatography tailored for specific applications.

  • What is the purpose of filtration?

    Filtration is a physical separation process used to remove solid particles from liquids or gases. The primary purpose of filtration is to obtain a clear liquid by separating insoluble solids from a mixture. This is achieved by passing the mixture through a filter medium, such as filter paper or a membrane, which allows the liquid to pass while retaining the solid particles. Filtration is commonly demonstrated by mixing sand and water, where the sand remains on the filter paper, and the clear water is collected below. This technique is essential in various fields, including chemistry, environmental science, and food processing, as it helps in purifying liquids and ensuring the quality of products.

  • What is crystallization used for?

    Crystallization is a purification technique used to separate and purify solid compounds from a solution. The process involves forming solid crystals from a saturated solution, which occurs when the solution is cooled or when the solvent evaporates. The key steps in crystallization include preparing a saturated solution by dissolving a solid in a solvent, followed by hot filtration to remove impurities. As the solution cools, pure crystals begin to form, which can then be collected through further filtration. This method is particularly useful in chemistry for obtaining high-purity samples of substances, as it effectively separates the desired compound from impurities based on differences in solubility.

  • What is solvent extraction?

    Solvent extraction is a separation technique used to isolate specific compounds from a mixture, typically involving the transfer of a solute from one solvent to another. This method is particularly effective for separating organic compounds from aqueous solutions. The process involves adding an organic solvent to the mixture, which selectively dissolves the target compound. After thorough mixing, the two layers (aqueous and organic) are allowed to separate, and the desired compound can be collected from the organic layer. Solvent extraction is widely used in various applications, including pharmaceuticals, environmental analysis, and chemical processing, as it allows for efficient separation and purification of compounds based on their solubility properties.

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Summary

00:00

Essential Purification Techniques for Chemistry Students

  • The video covers Basic Analytical Techniques for Standard 11, focusing on five purification methods: filtration, suction filtration, crystallization, and fractional crystallization.
  • The filtration method separates insoluble solids from liquids, demonstrated by mixing water and sand, using a funnel and filter paper to collect pure water.
  • For suction filtration, a Buckner funnel is used with a vacuum pump to separate small solid particles from liquids, ensuring efficient removal of moisture and impurities.
  • The crystallization method involves four steps: preparing a saturated solution, hot filtration, cooling the filtrate, and final filtration to collect pure crystals.
  • To prepare a saturated solution, dissolve a solid in a solvent until no more dissolves, then heat the solution on a tripod stand to evaporate impurities.
  • After cooling the hot filtrate, crystals form; these are collected by filtering again to separate them from the remaining liquid, known as mother liquor.
  • Fractional crystallization separates substances with different solubilities in the same solvent, allowing the less soluble solid to crystallize first, followed by the more soluble one.
  • The process requires dissolving both solids in a suitable solvent, allowing the less soluble solid to crystallize and be filtered out before the more soluble solid.
  • Each filtration step ensures that impurities are removed, resulting in pure solid samples collected on filter paper after both hot and cold filtration.
  • Understanding these techniques is essential for students in chemistry, particularly in higher education, where advanced methods like suction filtration are commonly used.

13:17

Crystallization and Distillation Techniques Explained

  • The process begins with cooling down the second crystal, which will be crystallized using filtration, employing the fraction crystallization method for purification.
  • Distillation involves converting a liquid sample into gas and then condensing it back into liquid, with three methods: simple distillation, fractional distillation, and distillation under reduced pressure.
  • The simple distillation setup includes a round bottom flask (RB flask), a stand, a tripod, a burner for heating, and a condenser connected via a side arm tube.
  • The condenser has an inner tube for vapor passage and an outer tube for water flow, with an inlet and outlet to maintain continuous cooling during the distillation process.
  • A mixture of two liquids with a significant boiling point difference (e.g., 40-50 degrees Celsius) is heated in the round bottom flask, monitored with a thermometer to track temperature changes.
  • As the mixture boils, vapors ascend into the condenser, where they cool and condense back into liquid, which is collected in a container below.
  • For fractional distillation, a fractionating column is added to the setup to separate liquids with boiling points differing by only 10-20 degrees Celsius, such as acetone (329 K) and benzene (353 K).
  • The fractionating column allows vapors to rise slowly, preventing mixing, ensuring that acetone and benzene can be collected separately in their respective containers.
  • The process involves heating the mixture until acetone vaporizes, then increasing the temperature to collect benzene, ensuring each component is purified without contamination.
  • Distillation under reduced pressure is used for liquids with high boiling points, allowing for lower temperature distillation, which prevents decomposition of sensitive compounds.

25:44

Techniques for Effective Liquid Separation

  • Distillation under reduced pressure involves lowering atmospheric pressure to decrease the boiling point of liquids, facilitating easier distillation of high boiling point substances.
  • The boiling point is defined as the temperature where the vapor pressure of a liquid equals atmospheric pressure, which is 760 mm of mercury.
  • Water boils at 100 degrees Celsius, meaning its vapor pressure equals atmospheric pressure at this temperature; reducing atmospheric pressure lowers the boiling point.
  • If atmospheric pressure is halved, water boils at 50 degrees Celsius; doubling the pressure raises the boiling point to 200 degrees Celsius.
  • Distillation methods include simple distillation, fractional distillation, and distillation under reduced pressure, each serving to purify components based on boiling points.
  • Solvent extraction is used to separate organic compounds from aqueous layers, requiring a separating funnel and shaking for 20 to 25 minutes to mix layers.
  • To extract iodine from an aqueous layer, an organic solvent like ether is added, and after shaking, the layers separate, allowing for extraction of the organic component.
  • Chromatography is a superior separation method involving stationary and mobile phases; stationary phases are solid materials, while mobile phases are volatile liquids or gases.
  • In column chromatography, a column of adsorbing material is prepared, and a mixture is placed on top, with a solvent running through to separate components based on adsorption rates.
  • Thin layer chromatography uses a glass plate coated with a stationary phase; samples are spotted above a baseline, and the mobile phase must not dip below this line during the process.

39:45

Chromatography Techniques for Sample Analysis

  • For thin layer chromatography (TLC), place the sample in an iodine container to develop color; components will travel distances for identification, similar to partition chromatography using vomit filter paper number 41.
  • In paper chromatography, draw a baseline on wet filter paper number 41, spot the sample above it, and place it in a small petri dish; the mobile phase will ascend, developing colors for analysis.
  • Calculate the RF value by dividing the distance traveled by the solute from the baseline by the distance traveled by the solvent; this ratio aids in identifying and purifying the sample.
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